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Isotope effect in gas-surface vibrational energy transfer: Cyclopropane and cyclopropane-d6 isomerization by the VEM technique

✍ Scribed by W. Yuan; R. Tosa; K.-J. Chao; B.S. Rabinovitch


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
364 KB
Volume
85
Category
Article
ISSN
0009-2614

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✦ Synopsis


The relauon between molecular structure and efticrcncy of wbratronal energy transfer between gas molecules rnd J surface has been ektcndcd to the pau cycloprop;lne/cyclopropanc~6

The latter ts less ciiictent to energy loss. as corresponds to Its greater wbratronal clgcnstatc dcnsrty Convcrscly, the probsbtbty of up-tnnsltlons as enhanced