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Vibrational energy relaxation in liquid N2-CO mixtures

โœ Scribed by S.R.J. Brueck; R.M. Osgood Jr.


Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
186 KB
Volume
18
Category
Article
ISSN
0030-4018

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๐Ÿ“œ SIMILAR VOLUMES


Vibrational energy relaxation in liquid
โœ S.R.J. Brueck; R.M. Osgood Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 689 KB

The vibrationaI energy relaxation rates of the liquid nitrogen-CO system have been measured by optically pumping the collision-induced fundamentalvibrational absorption band of liquid Nz with the output of an HBr TEA laser. A rad2atively dominated value of 56 f 10 s is found for the intrinsic nitrog

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The influence of small additions of tripropylamine on vibrational energy relaxation in C02-containing mixtures has been studied cspL-imentally. The rate constant for deactivation of the v3 mode of CO? by tripropybtine molecules has been measured.

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The vibrational relaxation of HCI in liquid xenon at -68ยฐC has been studied. Vibrationally excited HCI is created following UV photolysis of HCI. The rate of relaxation of HCl as a function of HCl mole fraction in liquid xenon is the same as the correspondingrate forgas phaseHCIat -68ยฐC. Similarly t

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Ohwrvation~ of the infrared fluorcsccncc of (quid or solid CO following; cxcitdtlon by :I frcqncncy-doublcti TCA CO? laser rwed ;I non-c?rponcntiJ decay curve for a pure CO saalplc. Vrbration,d rcld?rdtwn ant1 vlbrati0n.d dlffuslon conrtants wcrc dctcrmincd by ancllysing thcsc curves III the tempera