Vibrational energy relaxation of liquid deuterium chloride
โ Scribed by J. Chesnoy; D. Ricard
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 380 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
The energy rekstion of the lowest vibrational Ieke (U = 1) of liquid oxygen in the electronic ground state aas investigated \Cthin a wide temperature range (53.4 Ii < T < 96 R). The relaation time exhibits a peak vlllue of; = 3.1 ms around 65 I< and is shorter at loxcer and higher temperatures. The
The vibrationaI energy relaxation rates of the liquid nitrogen-CO system have been measured by optically pumping the collision-induced fundamentalvibrational absorption band of liquid Nz with the output of an HBr TEA laser. A rad2atively dominated value of 56 f 10 s is found for the intrinsic nitrog
A theory IS presen:ed for vlbratmnai energy relavatlon m polyatomlc molecular hquids mduced by Cor~ohs mteractlons, and applied to sereral bnear trlatomic molecules III mert solrents The predIcted rates are conststent with experImenta measurements on these systems.
Infrared double resonance and saturation techniques have both been used to measure the V-T relaxation of the 19 mode of CH3F in dilute solution in the cryogenic liquid hosts 02 and Ar. With the former technique, a relaxation time of 375 + 35 ns is found in liquid 02 while in liquid Ar the relaxation
The magnetic vibrational circular dichroism (MVCD) spectra of \(\mathrm{HCl}\) and \(\mathrm{DCl}\) are presented. The average rotational \(g\)-value of \(\mathrm{H}^{35} \mathrm{Cl}\) in the first excited vibrational states was determined to be 0.451 and 0.449 for the \(P\) and \(R\) branches, resp