✦ LIBER ✦

Vibrational energy distribution of CO in the oxidation of C on Pt

✍ Scribed by Moris Kori; Bret L. Halpern

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 588 KB
Volume: 98
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80196-1

No coin nor oath required. For personal study only.

✦ Synopsis

C'O.cw~t~d to its seventh vibrational level, is generated by C oxidation on Pt at 1000-1400 K. Analysis of its Fourier tran?torm IR emission spectrum suggestsa non-equilibrium,yct statistica1, vibrational distribution. A long-lived reaction complex mvolwng 2-3 Pt atoms 1s postulated.

📜 SIMILAR VOLUMES

Statistical energy partitioning in surfa

Statistical energy partitioning in surface reactions: the Pt-catalyzed oxidations of C and CO

✍ Bret Halpern; Moris Kori 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 673 KB

The fractions of energy partitioned between a desorbed product molecule and a solid catalyst are calculated for two surfacecatalyzed reactions according to a simple statistical model. It is shown that the experimentally measured energy disposal in the oxidation of CO on Pt is, to a first approximati

The metal-carbon stretch in the vibratio

The metal-carbon stretch in the vibrational spectrum of CO adsorbed on Pt{111}

✍ D. Hoge; M. Tüshaus; E. Schweizer; A.M. Bradshaw 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 577 KB

Multiquantum rotational transitions in t

Multiquantum rotational transitions in the mechanism of vibrational energy exchange: Application to CO*-CO

✍ Mirriam Lev-On; William E. Palke; Roger C. Millikan 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 509 KB

Tltc prcscnt study introduces ;I simplified method for :rcating vibrational-rot;ltionnl coupling during the collisionnl cschan~e of energy. This rorationnl couplinp modifies the vibrational cncrgy mismatch, wo and is a dominant cffcct, working to make the actu;ll energy mismatch smtilcr than the app

Energy distributions in vibrating system

Energy distributions in vibrating systems: The choice of coordinates

✍ John C. Whitmer 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 232 KB

CO oxidation on Pt: Model discrimination

CO oxidation on Pt: Model discrimination using experimental bifurcation behavior

✍ W. R. C. Graham; D. T. Lynch 📂 Article 📅 1987 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 930 KB

Chemiluminescent reaction at thermal ene

Chemiluminescent reaction at thermal energy: Vibrational distribution of CO+(A 2Π) from the C+ O2 reaction

✍ Masaharu Tsuji; Toshihiko Susuki; Minoru Endoh; Yukio Nishimura 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 280 KB

CO\*(A "ll-X 2P) emission produced from the C(2P) + O2 reaclm hss been observed al thermal cncrgy III a flowing afterdow apparatus. The relabve vIbrational population In the CO\*(A %I) state was dctcrrnmcd The avcngc fmctlon of VIbntional cncrgy dwrbulcd m CO+(A Zn).(/vJ. ws estimated to be 0.20 i 0