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Multiquantum rotational transitions in the mechanism of vibrational energy exchange: Application to CO*-CO

✍ Scribed by Mirriam Lev-On; William E. Palke; Roger C. Millikan

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
509 KB
Volume
24
Category
Article
ISSN
0009-2614

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✦ Synopsis

Tltc prcscnt study introduces ;I simplified method for :rcating vibrational-rot;ltionnl coupling during the collisionnl cschan~e of energy. This rorationnl couplinp modifies the vibrational cncrgy mismatch, wo and is a dominant cffcct, working to make the actu;ll energy mismatch smtilcr than the apparent energy discrepancy.Thc calculation is applied to the analysis of the CO*-CO system and it demonstrates the effect of collisions involving tr;msitions in which ti > I.

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