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Vibrational energy exchange between CO(v=1) and 14N2 and CO(v=1) and 15N2XXXured to 60 k in the gas phase

โœ Scribed by E.T. Handler; E.A. Gregory; R.M. Siddles; C.J.S.M. Simpson

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
418 KB
Volume
78
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

A laser fluorcscencr tcchniquc has been used to measure (Vv) cxchangc ratl?s between CO(u = 1) and t4Nz and l5 N, to GO K. At GS K exchsngc :o t 5Nz has 65 times the higher rate constant. Comparison with data for (VV) exchange in hquid N2 sllows that the isulatcd binary collision theory does not hold for the ase of CO@ = 1) and "NQ.

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