The nascent transient linewidths of the CO2 00'1, J-+OO"2, J-1 transitions were measured immediately following collisions with hot H and D atoms of 2.30 and 2.16 eV energy, respectively. All lineshapes were well fitted by Gaussian profiles, but were significantly broader than the room-temperature Do
Rotational—vibrational energy transfer in atom—polyatomic collisions: Li+CO2 in the 1 to 10 eV range
✍ Scribed by Eduardo Vilallonga; David A. Micha; J.Peter Toennies
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 519 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
A many-body approach to motecuhr collisions is applied to the L~icuhtion of vibrational-rotational transition probtlbilities of ionsstztttered from linear triztomic molecules_ The system Li+-CO2 has been chosen in order to comprtre the theoretical predictions with e..perimental resultr Good amment is found at scattering at&es greater than wice the rzinbow x&e. for the experimental collision erergiez.
📜 SIMILAR VOLUMES
Differentialandtotal state-to-state~sssectionsfoortheD+H,(u=O,j=O-3)~HD(u',j')+Hreactioninthe0.35-1.10eV collision energy range, have been calculated on the UTH surface using the QCT method. The results are commented on and compared to recent quantum mechanical calculations and to experimental measu