✦ LIBER ✦

Vibrational energy dissipation process in solution: picosecond laser photolysis studies of biphenylene

✍ Scribed by Yoshinori Hirata; Tadashi Okada

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 440 KB
Volume: 187
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(91)90413-4

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✦ Synopsis

Biphcnylcnc in various solvents is investigated by picosecond time-resolved absorption spectroscopy. The time dependence of the spectral shape of the vibrationally hot S.-S, absorption was analyzed by using the Urbach relation. Vibrational energy flow to the solvent molecules in the surroundings from the higher vibrational state of S, was proportional to the excess vibrational energy.

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