Picosecond laser photolysis studies on photochromic reactions of 1,2-bis(2,4,5-trimethyl-3-thienyl)maleic anhydride in solutions
โ Scribed by Hiroshi Miyasaka; Shigeru Araki; Akihiro Tabata; Takahiro Nobuto; Noboru Malaga; Masahiro Irie
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 636 KB
- Volume
- 230
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
Picosecond laser photolysis and transient absorption spectroscopy were applied to the direct observation of the photochromic reactions, such as ring-closure and ring-opening processes, of 1,2-bis(2,4,5-trimethyl-3-thienyl)maleic anhydride in solutions.
Both in the ring-closure and the ring-opening processes, very rapid ( < 10 ps) reaction channels were found. The mechanisms of ultrafast reaction processes and their solvent dependence were discussed.
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