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Laser-photolysis study of the photochemical primary processes of hydrogermanes in solution

โœ Scribed by Hisaharu Hayashi; Kunio Mochida

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
466 KB
Volume
101
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The mechanisms of the photochemical reactions of triphenylgermane and I-naphthylphenylmethylgermane in solution were studied. by mzwxement of the trzxnsient absorption spectra of their triplet states and germyl radicals. The rate constant for the chlorine abstraction reaction by each radical with CC14 was determined to be (6.6 f 1.0) X lo8 s-l mol-' dm3 at 28S"C.

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