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Vibrational deactivation of CO(υ = 1) by p-H2 and o-H2

✍ Scribed by Lise Lotte Poulsen; Gert D. Billing


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
764 KB
Volume
73
Category
Article
ISSN
0301-0104

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📜 SIMILAR VOLUMES


Mechanism of vibrational relaxation of C
✍ E.A. Andreev 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 540 KB

Vibrational relasatioo of CO2 by Hz0 has been studied theoretiully. Earlier theoretical works are critically analyzed. A new mechanism of V-R-T interaction is put forxvard and a functional equation for the probability factor is obtained. Collisions of CO2 with H-J 0 adsorbed on a solid surface are

Vibrational deactivation of CO by n-H2,
✍ A.J. Andrews; C.J.S.M. Simpson 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 420 KB

Probabilities for the (VT) and (VR) deactivation of CO have been calculated from relaxation times measured down to 77 K using laser fluorescence. Only in the case of deactivation by p-H2 is the (VR) process important; its rate exceeds that for (VT) deactivation between 320 K and 110 K.

Vibrational deactivation of N2(v = 1) BY
✍ D.C. Allen; E.T. Chandler; E.A. Gregory; R.M. Siddles; C.J.S.M. Simpson 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 565 KB

## Rate constants for the deacrivarion of N,(u= 1) by n-H, and by PHI between 300 and 80 K have ken measured using laser fluorescence from CO(u= 1). There is no n-HZ/p-Hz difference. N,(v=l) is deactivated about 3 times more slowly than is CO(u = 1). Comparison with results in liquid N, support t