Vibrational deactivation of CO(v = 1) by p-H2. The importance of the higher-order multipole moments
β Scribed by Lise Lotte Poulsen; Gert Due Billing
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 327 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0301-0104
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π SIMILAR VOLUMES
## Rate constants for the deacrivarion of N,(u= 1) by n-H, and by PHI between 300 and 80 K have ken measured using laser fluorescence from CO(u= 1). There is no n-HZ/p-Hz difference. N,(v=l) is deactivated about 3 times more slowly than is CO(u = 1). Comparison with results in liquid N, support t
The infrared emission observed from Hz0 or Co, when added to discharged oxygen containing Oz(r Zg> and C&(lA ) is shown to arise from their vibrational excitation in the quenching of Oz(\* $'). There was no ev&nce that O$'X> is quenched to the ground state rather than to the ' 4 state.
Rate constants have been determined at (298 \* 4) K for the reactions: and the relaxation processes: (lb) HF(u = 1) + HCN -HF(v = 0) + HCN Time-resolved HF(1,O) emission was observed following the photolysis of Fz with pulses from an excimer laser operating on XeCl ( h = 308 nm). Analysis of the
Nuclear quadrupole double resonance techniques have been used to investigate the NQR spectra of two compounds, Mo(CO)SP(C~H~)~ and cis-Mo(C0)4 [P(CeHs)s] 2. Nuclear quadrupole resonances for "MO and g7hLo were observed for the fust time and the absolute value of the ratio of the nuclear electric qua