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Vibrational conformational analysis of methyl fluoroacetate and methyl difluoroacetate

โœ Scribed by B.J. van der Veken; S. Truyen; W.A. Herrebout; G. Watkins


Book ID
107806912
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
317 KB
Volume
293
Category
Article
ISSN
0022-2860

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โœ Rose-Marie Moravie; Jacques Corset ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 421 KB

Through the analysis of the infrared spectra of methyl propionate recorded at several temperatures, two conformers were distinguished which were due to rotation about the C-C bond between the o carbon and carbonyl group. An equilibrium state is discussed, with an energy difference of 1.1 i 0.3 kcal