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Conformational analysis. 32. Conformational energies of methyl sulfide, methyl sulfoxide, and methyl sulfone groups

✍ Scribed by Eliel, Ernest L.; Kandasamy, Duraisamy.

Book ID
126028994
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
824 KB
Volume
41
Category
Article
ISSN
0022-3263

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## Abstract ^13^C‐NMR. and He (IΞ±) photoelectron spectra of alkyl phenyl sulfides, sulfoxides and sulfones have been used to probe how their conformations depend on the size of the alkyl groups R. The results are interpreted to indicate that in the sulfides the S, R‐bond is twisted out of the plana