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Chimera of Dimethylene Sulfone-, Methyl Sulfide-, and Methyl Sulfoxide-Linked Ribonucleotides and DNA

✍ Scribed by Baeschlin, Daniel K.; Hyrup, Birgitte; Benner, Steven A.; Richert, Clemens


Book ID
127094996
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
316 KB
Volume
61
Category
Article
ISSN
0022-3263

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## Abstract ^13^C‐NMR. and He (IΞ±) photoelectron spectra of alkyl phenyl sulfides, sulfoxides and sulfones have been used to probe how their conformations depend on the size of the alkyl groups R. The results are interpreted to indicate that in the sulfides the S, R‐bond is twisted out of the plana