The vibrational spectra and conformational behavior of methyl chloroacetate
โ Scribed by J.E. Katon; Deepali Sinha
- Book ID
- 113374025
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 564 KB
- Volume
- 33
- Category
- Article
- ISSN
- 1386-1425
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๐ SIMILAR VOLUMES
Through the analysis of the infrared spectra of methyl propionate recorded at several temperatures, two conformers were distinguished which were due to rotation about the C-C bond between the o carbon and carbonyl group. An equilibrium state is discussed, with an energy difference of 1.1 i 0.3 kcal
Infrared spectra (from 4000 to 400 cm-') of solid, liquid and gaseous l,l-diethylcyclopropane and Raman spectra of the condensed phases of this compound have been recorded. Evidence for two conformational isomers, one of which vanishes in the polycrystalline solid phase, is found in the spectral dat