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Vibrational spectra and conformational behavior of cyclohexylphosphine

โœ Scribed by Tain-Hen Pai; V. F. Kalasinsky


Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
531 KB
Volume
21
Category
Article
ISSN
0377-0486

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## Abstract The infrared and Raman spectra of solid, liquid and gaseous epifluorohydrin have been recorded. For the fluid phases, there are a number of spectral triplets which can be interpreted as arising from a __cis__ and two nonequivalent __gauche__ conformations. The number of bands which disa

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Through the analysis of the infrared spectra of methyl propionate recorded at several temperatures, two conformers were distinguished which were due to rotation about the C-C bond between the o carbon and carbonyl group. An equilibrium state is discussed, with an energy difference of 1.1 i 0.3 kcal