A many-body approach to motecuhr collisions is applied to the L~icuhtion of vibrational-rotational transition probtlbilities of ionsstztttered from linear triztomic molecules\_ The system Li+-CO2 has been chosen in order to comprtre the theoretical predictions with e..perimental resultr Good amment
Vibration-to-vibration energy transfer in COCO collisions
✍ Scribed by R.D. Sharma
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 689 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Vibration-t~v~ration energy transfer rates for collision between two CO molecules arc calculated. Rcsul~ obtained are compared with recent experiments and theoretical valtys. it is pointed out that none of the existing wIcuIatians gives a complete clccount of the available experimental data.
📜 SIMILAR VOLUMES
A simple approximate method for the vlbradon-vibration (V-V) energy-transrer process dunng coILnear collision of LWO CO molecules in the presence of an mrrared laser beam usmg a quasi-energy approach (non-perturbarive) is presented-The efrecl of radiation on V-V process is investigated by changing m
Intramolecular vibration-vibration energy transfer cross sections have beer. calculated for COz (0001) + H2,!Dz -+ COz(ll'0) + Hz/Dz,+ C02(10°0) + Hz/D\*, and-C02(20°0) + Hz/D2 based on the mechanism that the energy mismatch is transferred to the translational motion. For CO2 + Hz. the calculated cr
The cncrgy -rransfcr process, H&P,) f CO(O) -Hg('S~)+CO(v),hnsbccn nudisd by tie mexurcmen~oCthcLR flubrescerlce of CO. urine modulafed H&resonant radiation to excite Hg atoms. The cross section for each final vibrationallevelof v = 2 to 9 is 0.045, 0.091, 0.15, 0.17, 0.15, 0.065, 0.013, and 0.006 A
## Abstract The temperature dependence of the vibration–vibration energy transfer between the __v__~3~ mode of ^15^N^14^NO and the first vibrational level of CO was determined over a range of 680 to 1300°K using a shock tube. Several mixtures of ^15^N^14^NOCO were tested, diluted in 95% Ar. The re