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Very slow reactions, rates, and isotope effects in the bromination of 2-benzoylbutane

โœ Scribed by Lewis, Edward S.; Allen, James D.; Wallick, Earl T.


Book ID
126413788
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
984 KB
Volume
34
Category
Article
ISSN
0022-3263

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Kinetic isotope effects in the reactions
โœ Toshitsugu Yokota; Richard B. Timmons ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 462 KB ๐Ÿ‘ 1 views

The competitive reactions of Br atoms with CH, and CD, were studied over the temperature range of 562' to 637ยฐK. Over this temperature interval, the kinetic isotope effect, k,/k,, varied from 3.05 to 2.47 for the reactions Br + CH, -% HBr + CH, The rate constant ratio k,/k, , expressed in Arrhenius