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The Hydrogen Isotope Effect in the Bromination of 2-carbethoxycyclopentanone

โœ Scribed by R. P. Bell, J. A. Fendley and J. R. Hulett


Book ID
123675614
Publisher
The Royal Society
Year
1956
Tongue
English
Weight
638 KB
Volume
235
Category
Article
ISSN
0962-8444

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Anomalous kinetic hydrogen isotope effec
โœ M. A. Brusa; A. J. Colussi ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 400 KB

Rates of oxidation of XCOO-(X = H, D) by Brz in acid aqueous media were measured between 274 and 332 K. The derived Arrhenius parameters for both reactions log k ~( M -l S-') = (11.81 f 0.10) -(14.33 f 0.13)/0 log ~D ( M -' S-') = (13.77 f 0.13) -(17.62 f 0.04)/0 where 0 = 4.575T X kcal/mol, with (