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The Hydrogen Isotope Effect in the Bromination of 2-carbethoxycyclopentanone

โœ Scribed by Bell, R. P.; Fendley, J. A.; Hulett, J. R.


Book ID
120146219
Publisher
The Royal Society
Year
1956
Tongue
English
Weight
710 KB
Volume
235
Category
Article
ISSN
0962-8444

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Anomalous kinetic hydrogen isotope effec
โœ M. A. Brusa; A. J. Colussi ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 400 KB

Rates of oxidation of XCOO-(X = H, D) by Brz in acid aqueous media were measured between 274 and 332 K. The derived Arrhenius parameters for both reactions log k ~( M -l S-') = (11.81 f 0.10) -(14.33 f 0.13)/0 log ~D ( M -' S-') = (13.77 f 0.13) -(17.62 f 0.04)/0 where 0 = 4.575T X kcal/mol, with (