✦ LIBER ✦

Very low-pressure pyrolysis (VLPP) of t-butylmethyl ether

✍ Scribed by Kwang Yul Choo; David M. Golden; Sidney W. Benson

Publisher: John Wiley and Sons
Year: 1974
Tongue: English
Weight: 411 KB
Volume: 6
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550060503

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✦ Synopsis

Abstract

The thermal decomposition of t‐butylmethyl ether has been studied using the VLPP technique. The recommended Arrhenius parameters for the molecular elimination, reaction (1), are A(800°K) = 10^1 3, 9^ sec^−1^ and E~a~ (800°K) = 59.0 ± 1.0 kcal/mole. No radical reactions occur under the conditions used.
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These parameters are in good agreement with earlier experimental work and with theoretical estimates of both A and E.

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