✦ LIBER ✦

Very low-pressure pyrolysis (VLPP) of cyclopentene

✍ Scribed by Keith D. King

Publisher: John Wiley and Sons
Year: 1978
Tongue: English
Weight: 294 KB
Volume: 10
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550100110

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✦ Synopsis

The unimolecularity of the thermal dehydrogenation of cyclopentene has been confirmed using the technique of very low-pressure pyrolysis (VLPP). Application of RRKM theory shows that the experimental unirnolecular rate constants obtained over the temperature range of 942O-1152OK are consistent with the high-pressure Arrhenius parameters given by log (klsec-') = 13.35 -61/6 where B = 2.303 R T kcal/mol. These parameters are in good agreement with static and shock tube studies. No firm evidence could be found for any side reactions or reversibility under the experimental conditions used.

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