✦ LIBER ✦

Very low-pressure pyrolysis: VI. The decomposition of ethyl acetate

✍ Scribed by Peter C. Beadle; David M. Golden; S. W. Benson

Publisher: John Wiley and Sons
Year: 1972
Tongue: English
Weight: 289 KB
Volume: 4
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550040303

No coin nor oath required. For personal study only.

✦ Synopsis

The pyrolysis of ethyl acetate has been studied by the very low-pressure pyrolysis (VLPP) technique. The results obtained agree well with the previously determined high-pressure Arrhenius parameters where log k, = 12.6 -48.0/8. The rate constants given by these parameters have also been shown to be consistent with the predictions of the RRK and RRKM theories and demonstrate the applicability of the technique to the study of thermal decompositions.

📜 SIMILAR VOLUMES

Very low pressure pyrolysis of phenyl ac

Very low pressure pyrolysis of phenyl acetate

✍ E. Ghibaudi; A. J. Colussi 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 422 KB

The kinetics of the unimolecular decomposition of phenyl acetate into phenol and ketene, reaction (1): has been studied under very low-pressure conditions between 950 and 1120 K. In this range alternative processes such as the Fries rearrangement to o-hydroxyacetophenone or bond fission into phenox

Very low-pressure pyrolysis. VIII. The d

Very low-pressure pyrolysis. VIII. The decomposition of Di-t-amyl peroxide

✍ M. J. Perona; D. M. Golden 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 424 KB

The very low-pressure pyrolysis (VLPP) technique has been applied to the pyrolysis of di-t-amyl peroxide (DTAP) over the temperature range 523-633°K. VLPP yields a low-pressure rate constant, kuni The conversion of k,,, to k, , which must be made to calculate the Arrhenius parameters, is accomplishe

Very low-pressure pyrolysis (VLPP) of he

Very low-pressure pyrolysis (VLPP) of hex-1-ene. Kinetics of the retro-ene decomposition of a mono-olefin

✍ Keith D. King 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 457 KB

## Abstract The thermal unimolecular decomposition of hex‐1‐ene has been investigated over the temperature range of 915–1153 K using the technique of very low‐pressure pyrolysis (VLPP). The reaction proceeds via the competitive pathways of C~3~−C~4~ fission and retro‐ene elimination, with the latte

The Very low-pressure pyrolysis of 2-phe

The Very low-pressure pyrolysis of 2-phenylethylamine. The enthalpy of formation of the aminomethyl radical

✍ A. J. Colussi; S. W. Benson 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 447 KB

The thermal unimolecular decomposition of 2-phenylethylamine (PhCHZCHzNH,) into bensyl and aminomethyl radicals has been studied under very-low-pressure conditions, and the enthalpy of formation of the aminomethyl radicals, A H 7 , z p s ~ (HzNCHZ.) = 37.0 f 2.0 kcal/mol, hm been derived from the ki

The very low-pressure pyrolysis of pheny

The very low-pressure pyrolysis of phenyl methyl sulfide and benzyl methyl sulfide. The enthalpy of formation of the methylthio and phenylthio radicals

✍ A. J. Colussi; S. W. Benson 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 481 KB

The kinetics and mechanisms of the unimolecular decompositions of phenyl methyl sulfide (PhSCH,) and benzyl methyl sulfide (PhCHzSCH3) have been studied at very low pressures (VLFP). Both reactions essentially proceed by simple carbon-sulfur bond fission into the stabilized phenylthio (PhS. ) and be

Very low-pressure pyrolysis (VLPP) of pe

Very low-pressure pyrolysis (VLPP) of penta-1,3-dienes. Kinetics of the unimolecular 1,4-hydrogen elimination from cis-penta-1,3-diene

✍ Tam T. Nguyen; Keith D. King 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 323 KB

## Abstract The thermal unimolecular reactions of __cis__‐ and __trans__‐penta‐1,3‐diene (__c__‐PTD and __t__‐PTD) have been studied over the temperature range of 1002–1235 K using the technique of very low‐pressure pyrolysis (VLPP). __c__‐PTD decomposes via 1,4‐hydrogen elimination analogous to th