✦ LIBER ✦

Very-low-pressure pyrolysis (VLPP) of group IV (A) tetramethyls: Neopentane and tetramethyltin

✍ Scribed by Alan C. Baldwin; Karan E. Lewis; David M. Golden

Publisher: John Wiley and Sons
Year: 1979
Tongue: English
Weight: 642 KB
Volume: 11
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550110506

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✦ Synopsis

Abstract

The decomposition of neopentane was studied using the very‐low‐pressure pyrolysis (VLPP) technique at temperatures from 1000 to 1260 K. The derived Arrhenius parameters

are consistent with δ__H__~f~^0^(t‐butyl) = 8.4 kcal/mol. Using the above A factor, data on the decomposition of tetramethyltin yield DH^0^(Sn(CH~3~)~3~ ‐ CH~3~) = 69 ± 2 kcal/mol.

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