Vibrational dipole matrix elements and radiative transition probabilities for H,Se and HCS-have been evaluated from theoretical three-dimensional electric dipole moment and potential energy functions. The radiative lifetimes of the (u= 1, J=O) levels of HCS-have been calculated to be 3.5 ms (CH stre
Very long vibrational lifetimes in liquid O2 and N2
โ Scribed by G. Renner; M. Maier
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 315 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0009-2614
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The vibrationaI energy relaxation rates of the liquid nitrogen-CO system have been measured by optically pumping the collision-induced fundamentalvibrational absorption band of liquid Nz with the output of an HBr TEA laser. A rad2atively dominated value of 56 f 10 s is found for the intrinsic nitrog
## Abstract The temperature dependence of the vibrationโvibration energy transfer between the __v__~3~ mode of N~2~O and the first vibrational level of CO was determined over a range of 780 to 1400ยฐK using a shock tube. Several mixtures of COโN~2~O were tested, diluted in 95% Ar. The LandauโTeller