heptanes have been synthesized in a short route. These compounds containing benzamide or benzenesulfonamide groups are good substrates for microbial oxidation of unactivated carbons by B. bassiana.
Versatile Synthesis and Reactivity of Tropanes and Related Azabicycloalkanes
β Scribed by David StC. Black; Donald C. Craig; Gavin L. Edwards; Sean M. Laaman
- Book ID
- 102564962
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 101 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0045-2068
No coin nor oath required. For personal study only.
β¦ Synopsis
The four 5-alkenyl-1-pyrroline 1-oxide-5-carboxylic esters 1-4 undergo regioselective intramolecular cycloaddition to give the cycloadducts 5-8, which can be hydrogenolyzed to generate a range of azabicyclic compounds and unusual cyclic amino esters.
π SIMILAR VOLUMES
The versatile, hitherto unreported benzothiazol-2-ylcarbonylhydroximoyl chloride (2) was prepared by treatment of the corresponding sulfonium bromide 1 with sodium nitrite and hydrochloric acid in dioxane. Compound 2 reacts with o-aminothiopbenol and with o-phenylenediamine to afford the new ketones