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V–Cu Composite Oxide Catalyst for Transesterification of Dimethyl Carbonate with Phenol to Diphenyl Carbonate

✍ Scribed by Dongshen TONG; Tong CHEN; Jie YAO; Yue WANG; Gongying WANG; Dachuan SHI; Zheng LI; Zhiming CHEN

Book ID
108499129
Publisher
Elsevier Science
Year
2007
Weight
264 KB
Volume
28
Category
Article
ISSN
1872-2067

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A novel catalyst for transesterification
A novel catalyst for transesterification of dimethyl carbonate with phenol to diphenyl carbonate: samarium trifluoromethanesulfonate
✍ Mei Fuming; Li Guangxing; Nie Jin; Xu Huibi 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 39 KB

Samarium trifluoromethanesulfonate (Sm(OTf) 3 ) was found to be a novel catalyst for synthesis of diphenyl carbonate (DPC) by transesterification of dimethyl carbonate (DMC) with phenol. The best result was obtained by using Sm(OTf) 3 catalyst. The TON reached 21.8 mol DPC/mol Sm when the reaction w