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Cp2TiCl2 used as a catalyst for the transesterification between dimethyl carbonate and phenol to diphenyl carbonate

โœ Scribed by Hongying Niu; Jie Yao; Yue Wang; Gongying Wang

Book ID
108211493
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
90 KB
Volume
235
Category
Article
ISSN
1381-1169

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๐Ÿ“œ SIMILAR VOLUMES

A novel catalyst for transesterification
A novel catalyst for transesterification of dimethyl carbonate with phenol to diphenyl carbonate: samarium trifluoromethanesulfonate
โœ Mei Fuming; Li Guangxing; Nie Jin; Xu Huibi ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 39 KB

Samarium trifluoromethanesulfonate (Sm(OTf) 3 ) was found to be a novel catalyst for synthesis of diphenyl carbonate (DPC) by transesterification of dimethyl carbonate (DMC) with phenol. The best result was obtained by using Sm(OTf) 3 catalyst. The TON reached 21.8 mol DPC/mol Sm when the reaction w