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A new process for the synthesis of diphenyl carbonate from dimethyl carbonate and phenol over heterogeneous catalysts

โœ Scribed by Won Bae Kim; Jae Sung Lee

Book ID
110383845
Publisher
Springer US
Year
1999
Tongue
English
Weight
76 KB
Volume
59
Category
Article
ISSN
1011-372X

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Two-step synthesis of diphenyl carbonate
Two-step synthesis of diphenyl carbonate from dimethyl carbonate and phenol using MoO3SiO2 catalysts
โœ Zi-hua Fu; Yoshio Ono ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 626 KB

The transesterification of dimethyl carbonate with phenol to produce methyl phenyl carbonate was carried out in an autoclave using a variety of solid catalysts. MoO,/SiO, was found to have a very high activity for this transesterification. Thus, a 17.1% yield of methyl phenyl carbonate based on phen

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The mesoporous catalyst activities of supported molybdenum oxide for diphenyl carbonate (DPC) synthesis in liquid-phase transesterification of dimethyl carbonate (DMC) and phenol were investigated. The yields of DPC and methyl phenyl carbonate (MPC) were greatly improved when MoO 3 was supported on