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Transesterification of dimethyl carbonate with phenol to diphenyl carbonate over V2O5 catalyst

โœ Scribed by Dong-Shen Tong; Jie Yao; Yue Wang; Hong-Ying Niu; Gong-Ying Wang


Book ID
108212857
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
457 KB
Volume
268
Category
Article
ISSN
1381-1169

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A novel catalyst for transesterification
โœ Mei Fuming; Li Guangxing; Nie Jin; Xu Huibi ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 39 KB

Samarium trifluoromethanesulfonate (Sm(OTf) 3 ) was found to be a novel catalyst for synthesis of diphenyl carbonate (DPC) by transesterification of dimethyl carbonate (DMC) with phenol. The best result was obtained by using Sm(OTf) 3 catalyst. The TON reached 21.8 mol DPC/mol Sm when the reaction w