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Variable-Temperature and -Pressure Kinetics and Mechanism of the Cyclopalladation Reaction of Imines in Aprotic Solvent

✍ Scribed by Gómez, Montserrat; Granell, Jaume; Martinez, Manuel

Book ID
120020553
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
337 KB
Volume
16
Category
Article
ISSN
0276-7333

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Kinetics and mechanism of aminolysis of
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✍ Agu-Tõnis Talvik; Ants Tuulmets; Evi Vaino 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 52 KB 👁 2 views

Kinetic studies were carried out on the aminolysis reactions of substituted aliphatic esters in a variety of aprotic solvents. The reaction rate is strongly affected by inductive and steric effects of substituents in the acyl group, rising more than 10 4 -fold from cyanoacetate to trifluoroacetate.