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Solution behaviour, kinetics and mechanism of the acid-catalysed cyclopalladation of imines *

✍ Scribed by Gómez, Montserrat; Granell, Jaume; Martinez, Manuel

Book ID
120306810
Publisher
The Royal Society of Chemistry
Year
1998
Tongue
English
Weight
120 KB
Volume
1
Category
Article
ISSN
1472-7773

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The kinetics of the acid-catalysed hydrolysis of the [(imidazole)4Co(CO3) ] + ion was found to follow the rate law -dln[complex]/dt = k~K[H+]/(1 + K[H+]) in the 25-45 ~ range, [H +] 0.05-1.0 M range and I = 1.0 M. The reaction sequence consists of a rapid protonation equilibrium followed by the one-