The kinetics and mechanism of acid catalysed hydrolysis of lactams
β Scribed by Wan, Peter; Modro, Tomasz A.; Yates, Keith
- Book ID
- 120233599
- Publisher
- NRC Research Press
- Year
- 1980
- Tongue
- French
- Weight
- 602 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0008-4042
- DOI
- 10.1139/v80-391
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π SIMILAR VOLUMES
The kinetics of the acid-catalysed hydrolysis of the [(imidazole)4Co(CO3) ] + ion was found to follow the rate law -dln[complex]/dt = k~K[H+]/(1 + K[H+]) in the 25-45 ~ range, [H +] 0.05-1.0 M range and I = 1.0 M. The reaction sequence consists of a rapid protonation equilibrium followed by the one-
We recently reported' that acctanilide readily sulphonatcs in solutions of sulphuric acid > 70 per cent I& to form I+acetylsulphanilic acid , and noted that the rate of hydrolysis of this latter compound increased with increasing acidity beyond 80 per cent d= sulphuric acid. Ve have now prepared IG