𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Vapour pressures at several temperaturesTand excess functions atT= 298.15 K of (butanenitrile + ethanol or butan-1-ol)

✍ Scribed by R. Garriga; I. Putze; P. Pérez; M. Gracia

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
474 KB
Volume
27
Category
Article
ISSN
0021-9614

No coin nor oath required. For personal study only.

✦ Synopsis

Vapour pressures of (butanenitrile + ethanol or butan-1-ol) between the temperatures T=278.15 K and 323.15 K were measured by a static method. Excess enthalpies and volumes were also measured at T=298.15 K. Reduction of the vapour pressures to obtain activity coefficients and excess molar Gibbs free energies was carried out by Barker's method. Azeotropic mixtures with a minimum boiling temperature were observed over the whole temperature range. The experimental results are interpreted in terms of the specific interaction between the hydroxyl hydrogen of the alcohol molecule and the lone electron pair on the nitrogen atom.

📜 SIMILAR VOLUMES

Vapour pressures at several temperatures
Vapour pressures at several temperaturesTand excess functions atT=298.15 K of (butanenitrile+hexan-1-ol or octan-1-ol
✍ R. Garriga; P. Pérez; M. Gracia 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 397 KB

Vapour pressures of (butanenitrile+hexan-1-ol or octan-1-ol) between the temperatures T=288.15 K and 323.15 K were measured by a static method. Excess enthalpies and volumes were also measured at T=298.15 K. Reduction of the vapour pressures to obtain activity coefficients and excess molar Gibbs fre

Vapour pressures at several temperatures
Vapour pressures at several temperaturesTand excess functions atT= 298.15 K of (butanenitrile + propan-1-ol or propan-2-ol)
✍ R. Garriga; F. Sánchez; P. Pérez; M. Gracia 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 463 KB

Vapour pressures of (butanenitrile + propan-1-ol or propan-2-ol) at temperatures T between 278.15 K and 323.15 K were measured by a static method. Excess molar enthalpies and volumes were also measured at T=298.15 K. Following Barker's method, the activity coefficients and the excess molar Gibbs fre

Vapour pressures at several temperatures
Vapour pressures at several temperatures, and excess functions atT=298.15 K of (butanone + 2-butanol)
✍ R. Garriga; S. Martı́nez; P. Pérez; M. Gracia 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 206 KB

## Ž . Ž Vapour pressures of butanone q 2-butanol at eight temperatures between T s 278.15 and . 323.15 K were measured by a static method. Excess enthalpies and volumes were also measured at T s 298.15 K. The reduction of the vapour pressures to obtain activity coefficients and excess molar Gibbs

Excess functions atT= 298.15 K of (butan
Excess functions atT= 298.15 K of (butanenitrile +methanol, +pentan-1-ol, +heptan-1-ol, +nonan-1-ol, or +decan-1-ol)
✍ R. Garriga; J. Ilarraza; P. P érez; M. Gracia 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 407 KB

Vapour pressures, excess enthalpies, and excess volumes of (butanenitrile + methanol, + pentan-1-ol, + heptan-1-ol, + nonan-1-ol, or + decan-1-ol) were measured at a temperature T=298.15 K. Vapour pressures of mixtures containing methanol have also been measured at T=278.15 K, 288.15 K, 308.15 K, an

Vapour pressures at six temperatures bet
Vapour pressures at six temperatures between 278.15 K and 323.15 K and excess molar functions atT= 298.15 of (butanone + methanol or ethanol)
✍ R. Garriga; F. Sánchez; P. Pérez; M. Gracia 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 366 KB

Vapour pressures of (butanone + methanol or ethanol) at six temperatures between 278.15 K and 323.15 K were measured by a static method. Excess enthalpies and volumes of mixtures containing methanol were also measured at T=298.15 K. Reduction of the vapour pressures to obtain activity coefficients a

Excess volumes of (1,2-dichloroethane or
Excess volumes of (1,2-dichloroethane or 1,2-dibromoethane + butan-1-ol or butan-2-ol or 2-methylpropan-1-ol or 2-methylpropan-2-ol) at the temperatures 298.15 K and 313.15 K
✍ V. Rodrı́guez; H. Artigas; C. Lafuente; F.M. Royo; J.S. Urieta 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 161 KB

Excess volumes of (1,2-dichloroethane or 1,2-dibromoethane + each of several isomers of butanol) have been determined from density measurements at the temperatures \(298.15 \mathrm{~K}\) and \(313.15 \mathrm{~K}\) using an Anton-Paar dersimeter. The results show that excess volumes are positive over