Vapour pressures of (butanone + methanol or ethanol) at six temperatures between 278.15 K and 323.15 K were measured by a static method. Excess enthalpies and volumes of mixtures containing methanol were also measured at T=298.15 K. Reduction of the vapour pressures to obtain activity coefficients a
Vapour pressures at several temperatures, and excess functions atT=298.15 K of (butanone + 2-butanol)
✍ Scribed by R. Garriga; S. Martı́nez; P. Pérez; M. Gracia
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 206 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
✦ Synopsis
Ž
. Ž Vapour pressures of butanone q 2-butanol at eight temperatures between T s 278.15 and . 323.15 K were measured by a static method. Excess enthalpies and volumes were also measured at T s 298.15 K. The reduction of the vapour pressures to obtain activity coefficients and excess molar Gibbs energies was carried out by fitting the vapour pressure data to the Redlich᎐Kister correlation according to Barker's method. The thermodynamic properties of the mixtures of alcohols in butanone and in n-hexane are compared with the available data and discussed.
📜 SIMILAR VOLUMES
Vapour pressures of (butanenitrile + ethanol or butan-1-ol) between the temperatures T=278.15 K and 323.15 K were measured by a static method. Excess enthalpies and volumes were also measured at T=298.15 K. Reduction of the vapour pressures to obtain activity coefficients and excess molar Gibbs free
Vapour pressures of (butanenitrile + propan-1-ol or propan-2-ol) at temperatures T between 278.15 K and 323.15 K were measured by a static method. Excess molar enthalpies and volumes were also measured at T=298.15 K. Following Barker's method, the activity coefficients and the excess molar Gibbs fre
Vapour pressures of (butanenitrile+hexan-1-ol or octan-1-ol) between the temperatures T=288.15 K and 323.15 K were measured by a static method. Excess enthalpies and volumes were also measured at T=298.15 K. Reduction of the vapour pressures to obtain activity coefficients and excess molar Gibbs fre