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Vanadium-Catalyzed Asymmetric Epoxidation of Allylic Alcohols in Water
β Scribed by Malkov, Andrei V.; Czemerys, Louise; Malyshev, Denis A.
- Book ID
- 126120579
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 233 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0022-3263
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Vanadium catalysts bearing (+)-ketopinic acid-based chiral hydroxamic acids as constituent ligands are investigated in the asymmetric epoxidation of allylic alcohols. Chiral ligands lacking an N-substituent and those having a bulkier aryl group in the bornane skeleton provided better selectivity.
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