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Asymmetric epoxidation of allylic alcohols catalyzed by new chiral vanadium(V) complexes

✍ Scribed by Hsyueh-Liang Wu; Biing-Jiun Uang

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
256 KB
Volume
13
Category
Article
ISSN
0957-4166

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✦ Synopsis

Vanadium catalysts bearing (+)-ketopinic acid-based chiral hydroxamic acids as constituent ligands are investigated in the asymmetric epoxidation of allylic alcohols. Chiral ligands lacking an N-substituent and those having a bulkier aryl group in the bornane skeleton provided better selectivity.

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