Vanadium-Catalyzed Asymmetric Epoxidation of Allylic Alcohols Mediated by (+)-Norcamphor-Derived Hydroperoxide
β Scribed by Alessandra Lattanzi; Sandro Piccirillo; Arrigo Scettri
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 109 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-193X
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π SIMILAR VOLUMES
Vanadium catalysts bearing (+)-ketopinic acid-based chiral hydroxamic acids as constituent ligands are investigated in the asymmetric epoxidation of allylic alcohols. Chiral ligands lacking an N-substituent and those having a bulkier aryl group in the bornane skeleton provided better selectivity.
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