The effects of relative orientation on collision and reaction dynamics can be examined by characterizing the unimolecular decay of van der Waals complexes. Most commonly, decomposition is initiated by exciting one of the monomers within a complex, and the relative orientation is defined by the zero-
Van der Waals Onteractions in molecular complexes of tetracyanoethylene
✍ Scribed by Marie José Mantione
- Publisher
- Springer
- Year
- 1969
- Tongue
- English
- Weight
- 408 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1432-2234
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## Abstract The __T__Δ__S__^0^ term has been estimated for various types of van der Waals molecules and its importance for the stability predictions has been demonstrated. With hydrogen‐bonded complexes the absolute values of Δ__H__^0^ and __T__Δ__S__~0~ are comparable at 289°K. With true van der W