✦ LIBER ✦

Role of entropy in formation of van der Waals complexes

✍ Scribed by P. Hobza; P. Čársky; R. Zahradník

Publisher: John Wiley and Sons
Year: 1979
Tongue: English
Weight: 198 KB
Volume: 16
Category: Article
ISSN: 0020-7608
DOI: 10.1002/qua.560160206

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✦ Synopsis

Abstract

The T__Δ__S^0^ term has been estimated for various types of van der Waals molecules and its importance for the stability predictions has been demonstrated. With hydrogen‐bonded complexes the absolute values of Δ__H__^0^ and T__Δ__S~0~ are comparable at 289°K. With true van der Waals molecules the T__Δ__S^0^ term even represents a dominant contribution to Δ__G__^0^.

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