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A note about the role of entropy in the formation of van der Waals complexes

✍ Scribed by Zdenêk Slanina

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
151 KB
Volume
95
Category
Article
ISSN
0009-2614

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✦ Synopsis

The recently developed concept of entropy-controlled formation of van der Waais complexes based on standard molar changes of enthalpy and entropy has been found unsatisfactory. A thermodynamically consistent trcxtment shows that actual molar chanses of enthalpy and entropy can depend strongly on esperimental conditions_

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