๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Van der Waals complexes of the bichromophore spirobifluorene

โœ Scribed by Niels A. van Dantzig; Piotr Piotrowiak; Donald H. Levy

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
552 KB
Volume
223
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

โœฆ Synopsis

Van der Waals complexes of the bichromophore spirobifluorene with argon, nitrogen, water, methanol, and acetonitrile were studied in a supersonic jet. The 1: 1 complexes have two origin transitions which are shifted to the red and to the blue of the bare bichromophore origin. These spectral shifts are discussed in terms of the dispersive interactions in a three-body cluster. Larger argon clusters are identified by broad features which are caused by the spectral overlap of many origin transition. A model of vibronic coupling is suggested to explain the broadened features in some of the spectra.

๐Ÿ“œ SIMILAR VOLUMES

The electronic spectra of argon-tetracen
The electronic spectra of argon-tetracene van der waals complexes
โœ Ian Raitt; Anne M. Griffiths; Philip A. Freedman ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 370 KB

A simple relatronship is shown to occur between spectral line position and the number of bound argon atoms in the electronic spectrum of argon-tetracene van der Waals molecules, in contrast to the conclusion of other workers. We show that bondmg information may be obtained from such spectra

Infrared Spectrum of the CO-Xe van der W
Infrared Spectrum of the CO-Xe van der Waals Complex
โœ J.W.C. Johns; Z. Lu; R.W. Mckellar ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 351 KB

The first reported spectrum of the \(\mathrm{CO}-\mathrm{Xe}\) van der Waals complex has been studied in the 4.7\(\mu \mathrm{m}\) region of the \(\mathrm{CO}\) fundamental band using a long-path ( \(104 \mathrm{~m}\) ) low-temperature ( \(110 \mathrm{~K}\) ) static absorption cell and a high-resolu

Potential characteristics of the mercury
Potential characteristics of the mercury-methane van der Waals complex
โœ Marie-Christine Duval; Benoit Soep ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 593 KB

The Hg-CH4 van der Waals complex has been studied in a supersonic jet expansion, in transitions correlated with the 6 'SO+6 "PI mercury transitions. Fluorescence excitation spectra and action spectra have been recorded to analyse the corresponding transitions X-A and X+B. Through isotopic substituti

Solvent shifts in van der waals complexe
Solvent shifts in van der waals complexes of perylene
โœ John C. Ketteley; Jeffrey W. Oram; T.Frank Palmer; John P. Simons; A.Terry Amos ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 584 KB

The solvation and structure of vdW complexes formed in supersonic free-jet expansions of perylene with rare gas atoms and organic "solvent" molecules, using helium as carrier gas, have been investigated. The complexes were probed and analysed by combining laser-induced fluorescence spectroscopy with

UV spectroscopy of perylene-CO van der W
UV spectroscopy of perylene-CO van der Waals complexes
โœ Craig L. Perkins; Elizabeth Perez; Kenneth M. Beck ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 771 KB

A preliminary study of perylene-CO van der Waals complexes has been conducted. The spectroscopy of the major in-plane and out-of-plane features ofthe I : 1 and 1:2 perylene-CO aggregates hasbeen analyzed. Little perturbation to the G 'butterfly" outof-plane mode is seen in the complex, indicating th