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Valence Tautomerism: New Challenges for Electroactive Ligands (Eur. J. Inorg. Chem. 15/2005)

โœ Scribed by Emilia Evangelio; Daniel Ruiz-Molina

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
77 KB
Volume
2005
Category
Article
ISSN
1434-1948

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โœฆ Synopsis

Abstract

The cover picture shows the potential energy curves for a generic valence tautomeric complex with a schematic representation emphasizing the intramolecular electron transfer between the metal ion and the ligand, which can be induced by different external stimuli such as temperature, pressure or irradiation. The diagram is accompanied by a representation of the different redoxโ€active ligands involved in valence tautomerism that are presented in the Microreview by E. Evangelio and D. Ruizโ€Molina on p. 2957 ff.

๐Ÿ“œ SIMILAR VOLUMES

Valence Tautomerism: New Challenges for
Valence Tautomerism: New Challenges for Electroactive Ligands
โœ Emilia Evangelio; Daniel Ruiz-Molina ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 366 KB

## Abstract Valence tautomeric complexes combine redoxโ€active ligands and transition metal ions with two or more accessible oxidation states, exhibiting two nearly degenerated electronic states with localized electronic structures. Charge distribution in such electronic isomers has an appreciable s