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Synthesis and Characterisation of New Iridium Complexes with the (4S)-2-[2-(Diphenylphosphanyl)phenyl]-4-isopropyl-1,3-oxazoline Ligand That Catalyse Asymmetric Michael Reactions (Eur. J. Inorg. Chem. 9/2005)

✍ Scribed by Daniel Carmona; Joaquina Ferrer; Mónica Lorenzo; Fernando J. Lahoz; Isabel T. Dobrinovitch; Luis A. Oro

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
85 KB
Volume
2005
Category
Article
ISSN
1434-1948

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Synthesis and Characterisation of New Ir
Synthesis and Characterisation of New Iridium Complexes with the (4S)-2-[2-(Diphenylphosphanyl)phenyl]-4-isopropyl-1,3-oxazoline Ligand That Catalyse Asymmetric Michael Reactions
✍ Daniel Carmona; Joaquina Ferrer; Mónica Lorenzo; Fernando J. Lahoz; Isabel T. Do 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 153 KB 👁 1 views

## Abstract The chiral iridium compounds [IrCl(COE){(__S__)‐PN}] {COE = cyclooctene, PN = (4__S__)‐2‐[2‐(diphenylphosphanyl)phenyl]‐4‐isopropyl‐1,3‐oxazoline, (1)}, [Ir(acac)ClH{(__S__)‐PN}] {Hacac = acetylacetone, (2)} and [Ir{(__S__)‐PN}~2~]A {A = Cl (3a,b); BF~4~ (4a,b); PF~6~ (5a,b)} have been