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Valence Tautomerism: New Challenges for Electroactive Ligands

✍ Scribed by Emilia Evangelio; Daniel Ruiz-Molina


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


Valence Tautomerism: New Challenges for
✍ Emilia Evangelio; Daniel Ruiz-Molina πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 366 KB

## Abstract Valence tautomeric complexes combine redox‐active ligands and transition metal ions with two or more accessible oxidation states, exhibiting two nearly degenerated electronic states with localized electronic structures. Charge distribution in such electronic isomers has an appreciable s

Valence Tautomerism: New Challenges for
✍ Emilia Evangelio; Daniel Ruiz-Molina πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 77 KB

## Abstract **The cover picture shows** the potential energy curves for a generic valence tautomeric complex with a schematic representation emphasizing the intramolecular electron transfer between the metal ion and the ligand, which can be induced by different external stimuli such as temperature,