𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Valence isomerizations of diademane II: Transition metal and acid catalyzed rearrangements

✍ Scribed by Armin de Meijere


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
219 KB
Volume
15
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


The Mechanistic Puzzle of Transition-Met
✍ Cristina Nieto-Oberhuber; Salome Lopez; Eloisa Jimenez-Nunez; Antonio M. Echavar 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 8 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

The Mechanistic Puzzle of Transition-Met
✍ Cristina Nieto-Oberhuber; Salomé López; Eloísa Jiménez-Núñez; Antonio M. Echavar 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 611 KB

## Abstract Three pathways actually compete in metal‐catalyzed cyclizations of enynes in which the metal selectively activates the alkyne: an endocyclic process and two __exo__‐cyclizations, one proceeding by __anti__ attack of the alkene and a second one resulting in a __syn__ addition. Although c

Transition metal-catalyzed isomerization
✍ James V. Crivello; Surésh K. Rajaraman 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 194 KB 👁 1 views

Alkyl allyl ethers undergo facile thermally induced isomerization to alkyl 1-propenyl ethers in the presence of Group VIII transition metal carbonyl compounds as catalysts. The addition of a silane containing a Si-H bond to these systems results in a catalyst system that is capable of not only isome

Transition metal-catalyzed tandem isomer
✍ James V. Crivello; Surésh K. Rajaraman 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 227 KB 👁 1 views

In the presence of organosilanes, dicobalt octacarbonyl catalyzes the polymerization of alkyl allyl ethers to give high molecular weight polymers. This article reports the results of a detailed mechanistic study of this new polymerization reaction. The evidence obtained in this study supports a step