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Transition metal-catalyzed isomerization and polymerization of allylic and enolic ethers

✍ Scribed by James V. Crivello; Surésh K. Rajaraman

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
194 KB
Volume
35
Category
Article
ISSN
0887-624X

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✦ Synopsis

Alkyl allyl ethers undergo facile thermally induced isomerization to alkyl 1-propenyl ethers in the presence of Group VIII transition metal carbonyl compounds as catalysts. The addition of a silane containing a Si-H bond to these systems results in a catalyst system that is capable of not only isomerizing the allyl ether to the 1propenyl ether, but further results in the polymerization of these later compounds. High molecular weight polymers can be obtained directly from the alkyl allyl ether in a single step. The scope and limitations of these polymerizations are described.

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