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The Mechanistic Puzzle of Transition-Metal-Catalyzed Skeletal Rearrangements of Enynes

✍ Scribed by Cristina Nieto-Oberhuber; Salome Lopez; Eloisa Jimenez-Nunez; Antonio M. Echavarren

Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

The Mechanistic Puzzle of Transition-Met
The Mechanistic Puzzle of Transition-Metal-Catalyzed Skeletal Rearrangements of Enynes
✍ Cristina Nieto-Oberhuber; Salomé López; Eloísa Jiménez-Núñez; Antonio M. Echavar 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 611 KB

## Abstract Three pathways actually compete in metal‐catalyzed cyclizations of enynes in which the metal selectively activates the alkyne: an endocyclic process and two __exo__‐cyclizations, one proceeding by __anti__ attack of the alkene and a second one resulting in a __syn__ addition. Although c