UV Absorption Spectrum and Rate Constant for Self-Reaction of Silyl Radicals
β Scribed by Baklanov, Alexey V.; Krasnoperov, Lev N.
- Book ID
- 126855777
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 79 KB
- Volume
- 105
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
A flash photolysis technique has been used to measure the gas phase UV absorption cross-sections for C2H,02\* radicals over the wavelength range 215 -300 nm. Kinetic absorption spectroscopy was then employed to study the self-reaction of these radicals. The measured absorption cross-section at 250 n
## Abstract A flash photolysis setup coupled to UV absorption spectrometry detection was used to measure the UV absorption spectra of the (CH~3~)~2~(CH~2~O~2~.)CC(O)C(CH~3~)~3~ and (CH~3~)~2~(CH~2~O~2~.)CC(O)CH~3~ radicals between 207 and 290 nm. The selfβreaction rate constants of these radicals w